Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact:

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Paper | Special issue | Vol 37, No. 3, 1994, pp.1637-1644
Published online, 1st January, 1970
DOI: 10.3987/COM-93-S130
Kinetics of Hydrolysis of 1,3,5-Triazine in Mildly Acidic Media

Marina Privman and Petr Zuman*

*Department of Chemistry, Clarkson University, Postdam, NY 13699-5810, U.S.A.


Acid catalyzed hydrolysis of 1,3,5-triazine at pH 2 to 5 is governed by the rate of the ring opening. This follows from the value of the dissociation constant involved (pKa 2.7 at μ = 0.5 and pKa 2.3 at μ = 0.1), from the lack of pH-dependence of concentration of 1,3,5-triazine at t = 0, and from the irreversibility of the studied reaction.