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Communication | Regular issue | Vol 38, No. 1, 1994, pp.35-39
Published online, 1st January, 1970
DOI: 10.3987/COM-93-6558
Synthesis and Stereospecific Fragmentation of 3-Thiabicyclo[3.1.0]hexane 3,3-Dioxides

Hsi-Hwa Tso,* Li-Hong Tseng, and Yu-Ying Yu

*Institutue of Chemistry, Academia Sinica, 128, Yan-Chiu-Yuan Road, Sec II, Nankang, Taipei,11529, Taiwan, R.O.C.


Synthesis of new stereoisomeric 3-thiabicyclo[3.1.0]hexane 3,3-dioxides and experimental proof of their fragamentation to 1,4-dienes by a concerted, disrotatory process are described.