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Communication | Regular issue | Vol 36, No. 8, 1993, pp.1739-1742
Published online, 1st January, 1970
DOI: 10.3987/COM-93-6408
An Interesting Chemoselectivity in Palladation of Aromatic Bromides

Yuusaku Yokoyama, Mitsuru Takashima, Chitose Higaki, Kazuko Shidori, Shoko Moriguchi, Chizuru Ando, and Yasuoki Murakami*

*School of Pharmaceutical Sciences, Toho University, 2-2-1, Miyama, Funabashi, Chiba 274-8510, Japan


The reaction of various aromatic bromides with ethyl acrylate in the presence of stoichiometric amount of Pd(OAc)2 gave the vinylated products without affecting the carbon-bromine bond.