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Paper | Regular issue | Vol 36, No. 8, 1993, pp.1851-1857
Published online, 1st January, 1970
DOI: 10.3987/COM-93-6386
Inclusion Complex Formation between a Novel Anionic Cyclophane and Cationic Aromatic Guests in Aqueous Solution

Muneharu Miyake, Makoto Kirisawa, and Kenji Koga*

*Faculty of Pharmaceutical Sciences, University of Tokyo,Hongo, Bunkyo-ku, Tokyo 113, Japan


1H-Nmr spectral studies have shown that a negatively charged cyclophane (2) having eight carboxylate groups that are bonded directly on the aromatic rings forms 1:1 inclusion complexes selectively with positively charged aromatic compounds as guests in alkaline water.