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Communication | Special issue | Vol 35, No. 1, 1993, pp.37-40
Published online, 1st January, 1970
DOI: 10.3987/COM-92-S4
Diels-Alder Cycloaddition of 2(1H)-Pyridones Having Two Electron-Withdrawing Groups with Electron Deficient Dienophile

Hiroto Nakano and Hiroshi Hongo*

*Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, Japan


The first examples are presented of Diels-Alder cycloadditions of 2(1H)-pyridones having two electron-withdrawing groups on the ring, with electron deficient dienophiles, and the adducts obtained may act as dienophiles leading to richly functionalized, bridged, and polycyclic azacompounds, under high pressure conditions.