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Communication | Regular issue | Vol 36, No. 4, 1993, pp.665-669
Published online, 1st January, 1970
DOI: 10.3987/COM-92-6289
Nucleoside Synthesis from Furanoid Glycals

Hiroshi Kawakami,* Takashi Ebata, Koshi Koseki, Koji Okano, Katsuya Matsumoto, and Hajime Matsushita

*Life Science Research Laboratory, Japan Tobacco Inc., 6-2, Umegaoka, Midori-ku, Yokohama, Kanagawa 227-8512, Japan

Abstract

Reaction of furanoid glycals with PhSCl afforded 1-chlorosugars, which were used for condensation reaction with silylated uracil in the presence of SnCl4. These two reactions proceeded in a highly stereoselective manner.