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Communication | Regular issue | Vol 36, No. 4, 1993, pp.661-664
Published online, 1st January, 1970
DOI: 10.3987/COM-92-6279
First Asymmetric Diels-Alder Reactions in the Vinylhetarene Series: Cycloadditions with Vinylindoles to Enantiomerically Pure Carbazole Derivatives

Ulf Pindur,* Gundula Lutz, Werner Massa, and Ludger Schröder

*Institut für Pharmaize, Fachbereich Chemie und Pharmazie, Universität Maintz, Saarstrasse 21, D-6500 Maintz, Germany

Abstract

The first asymmetric Diels-Alder reactions of some 3- and 2-vinylindoles with (N-propenoyl)bornane-10,2-sultam are described. The experimental results are indicative of high to sufficient π-facial diastereoselectivity.