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Communication | Regular issue | Vol 36, No. 3, 1993, pp.427-430
Published online, 1st January, 1970
DOI: 10.3987/COM-92-6232
On the Regioselectivity in the Silyl Group Directed Baeyer-Villiger Reaction

Toshiaki Aida, Morio Asaoka,* Syuzo Sonoda, and Hisashi Takei

*Department of Life Chemistry, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8501, Japan

Abstract

In the Baeyer-Villiger reaction of 3,5-bis-silylated cyclohexanones, preferential migration of the less substituted α-carbon was observed.