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Paper | Regular issue | Vol 34, No. 5, 1992, pp.965-977
Published online, 1st January, 1970
DOI: 10.3987/COM-92-5972
Application of Photoamination to Synthesis of Benzylisoquinolines, Aporphins, and Isopavines

Masahide Yasuda,* Shuichi Hamasuna, Katsuhiko Yamano, Jun-ichi Kubo, and Kensuke Shima

*Department of Industrial Chemistry, Faculty of Engineering, Miyazaki University, Gakuen-Kibanadai, Miyazaki 889-21, Japan

Abstract

The preparation of benzylisoquinolines, isopavines, and aporphines was performed by the photoamination of stilbene, p-methoxystilbene, and phenanthrene with amino alcohols, aminoacetal, allylamine in the presence of dicyanobenzene followed by the cyclization with BF3 or CF3SO3H.