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Paper | Regular issue | Vol 32, No. 11, 1991, pp.2161-2192
Published online, 1st January, 1970
DOI: 10.3987/COM-91-5841
Stereochemical Characteristics of SET-promoted Photochemical Reactions of Dihydroisoquinolinium Salts

In-Seop Cho, Shirley S. S. Chang, Chihmei Ho, Chao-Pin Lee, Herman L. Ammon, and Patrick S. Mariano*

*Department of Chemsitry and Biochemistry, University of Maryland, College Park, MD 20742, U.S.A.


Single electron transfer (SET) promoted photocyclization reactions of a series of silylbenzyl- and silylalkenyl-dihydroisoquinolinium perchlorates have been explored in order to evaluate the extent and source of stereochemical control in these N-heterocycle forming, diradical cyclization processes.