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Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
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January 13, 2023
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Communication | Regular issue | Vol 32, No. 8, 1991, pp.1483-1486
Published online, 1st January, 1970■ Total Synthesis of Euryfuran via Two Sequential Furan Ring Transfer Reaction
Published online, 1st January, 1970
DOI: 10.3987/COM-91-5794
■ Total Synthesis of Euryfuran via Two Sequential Furan Ring Transfer Reaction
Ken Kanematsu* and Seizo Soejima
*Institute of Sythetic Organic Chemistry,Faculty of Pharmaceutical Sciences, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka 812-8582, Japan
Abstract
Total synthesis of the marine natural product euryfuran (4) via two sequential furan ring transfer reaction is presented. Key elements of the reaction pathway include as follows: 1) the preparation of propargyl ethers (5c), (10b), and (17c), and its transformation to allylic alcohols (6), (11) and (18), 2) introduction of the angular alkyl group via [3,3] sigmatropic rearrangement.
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