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Paper | Regular issue | Vol 32, No. 6, 1991, pp.1089-1099
Published online, 1st January, 1970
DOI: 10.3987/COM-90-5626
The Studies of Carbenoid Reactions of α-O-Allyl- or α-N-Allyl-α’-diazopropanone Derivatives Catalyzed by Various Metal Ions

Yung-Son Hon* and Rong-Chi Chang

*Institutue of Chemistry, Academia Sinica, 128, Yan-Chiu-Yuan Road, Sec II, Nankang, Taipei,11529, Taiwan, R.O.C.


Both cupric acetylacetonate and palladium (II) acetate are good catalysts to induce the carbon-carbon double bond addition reaction for α-O-allyl- or α-N-allyl-α’-diazopropanone derivatives. The heteroatom did not play an important role in enhancing the carbon-hydrogen bond insertion for compound (3).