Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Paper | Regular issue | Vol 31, No. 12, 1990, pp.2219-2224
Published online, 1st January, 1970
DOI: 10.3987/COM-90-5597
Oxidation Chemistry of cis-2-(3-Furylidene)ethanol

William E. Fristad and Leo A. Paquette*

*Evans Chemical Laboratories, The Ohio State University, 120 W. 18th Avenue, Columbus, Ohio 43210, U.S.A.

Abstract

Submission of the tri-n-butylstannylmethyl ether (9) of furylcarbinol (8) to Still rearrangement leads stereoselectively to 10 as the exclusive product. The cis-oriented nature of the hydroxyethyl and 3-furyl functional groups in 10 is cause for ready ring closure either to bensofuran (10) or lactone (13) depending upon conditions.