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Paper | Regular issue | Vol 31, No. 8, 1990, pp.1505-1511
Published online, 1st January, 1970■ Palladium-catalyzed Reaction of 3-Bromoindole Derivative with Allyl Esters in the Presence fo Hexa-n-butyldistannane
Published online, 1st January, 1970
DOI: 10.3987/COM-90-5441
■ Palladium-catalyzed Reaction of 3-Bromoindole Derivative with Allyl Esters in the Presence fo Hexa-n-butyldistannane
Yuusaku Yokoyama, Masato Ikeda, Masaaki Saito, Tomoko Yoda, Hideharu Suzuki, and Yasuoki Murakami*
*School of Pharmaceutical Sciences, Toho University, 2-2-1, Miyama, Funabashi, Chiba 274-8510, Japan
Abstract
The palladium-catalyzed cross-coupling reaction of ethyl 3-bromo-1-tosylindole-2-carboxylate (9) with a variety of substituted allylic acetates or carbonates (10) in the presence of hexa-n-butyldistannane (6) gave 3-allylated indoles (11) in high yields.
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