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Communication | Special issue | Vol 30, No. 1, 1990, pp.353-357
Published online, 1st January, 1970
DOI: 10.3987/COM-89-S66
Preparation of Optically Acyive 1,3,2-Oxathiaphosphorinanes Using (-)-10-Mercaptoisoborneol as a Chiral Source

Tamiko Takahashi, Makoto Matsui, Naoko Maeno,* Toru Koizumi,* and Motoo Shiro

*Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University, 2630 Sugitani, Toyama, Toyama 930-0194, Japan


Optically active 1,3,2-oxathiaphosphorinanes (3) and (4) were prepared from (-)-10-mercaptoisoborneol (1) and phosphorus dichlorides [RP(X)Cl2] (2). The configuration at phosphorus in these derivatives was assigned on the basis of their 1H nmr spectral data and X-ray diffraction analysis of 4f.