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Communication | Special issue | Vol 30, No. 1, 1990, pp.347-351
Published online, 1st January, 1970
DOI: 10.3987/COM-89-S64
Reaction of Triheteroarylphosphines with Organolithium Reagents Concurrent Ligand Exchange and Ligand Coupling

Yuzuru Uchida,* Yoshikazu Takaya, and Shigeru Oae*

*Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku,Osaka, Osaka 535, Japan


Reaction of tri(2-benzothiazyl)phosphine or tri(2-pyridyl)phosphine with aryl- or heteroaryllithium compounds in THF affords 2,2’-bibenzothiazyl or 2,2’-bipyridyl by ligand coupling in good yields.