Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact:

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Special issue | Vol 30, No. 1, 1990, pp.283-286
Published online, 1st January, 1970
DOI: 10.3987/COM-89-S34
Intra- and Intremolecular Palladium-Catalyzed Asymmetric Allylations of Chiral Enamines

Kunio Hiroi* and Jun Abe

*Department of Synthetic Organic Chemistry, Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, Japan


Stereochemistry of intramolecular palladium-catalyzed asymmetric allylations of chiral enamines involving allylating species in the molecules is discussed, compared with that of intermolecular reactions. The mechanistic pathway for this asymmetric induction is proposed on the basis of the stereochemical results.