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Zenichi Yoshida (1925-2023)
Zenichi Yoshida (1925-2023)
Professor. Zenichi Yoshida,
a member of the Honorary Advisors of HETEROCYCLES (1975-1998),
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May 11, 2023
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Communication | Special issue | Vol 30, No. 1, 1990, pp.283-286
Published online, 1st January, 1970■ Intra- and Intremolecular Palladium-Catalyzed Asymmetric Allylations of Chiral Enamines
Published online, 1st January, 1970
DOI: 10.3987/COM-89-S34
■ Intra- and Intremolecular Palladium-Catalyzed Asymmetric Allylations of Chiral Enamines
Kunio Hiroi* and Jun Abe
*Department of Synthetic Organic Chemistry, Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, Japan
Abstract
Stereochemistry of intramolecular palladium-catalyzed asymmetric allylations of chiral enamines involving allylating species in the molecules is discussed, compared with that of intermolecular reactions. The mechanistic pathway for this asymmetric induction is proposed on the basis of the stereochemical results.
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