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Paper | Special issue | Vol 30, No. 1, 1990, pp.487-492
Published online, 1st January, 1970
DOI: 10.3987/COM-89-S25
Lithiated 2-Methyl-5-Phenyloxizoles, Formation and Reactions with Electrophiles

Choji Kashima,* Hideki Arao, and Rieko Okada

*Department of Chemistry, University of Tsukuba, 1-1-1 Ten-nodai, Tsukuba-shi, Ibaraki, 305-8571, Japan

Abstract

The methyl group of 2-methyl-5-phenyloxazole (1) has been lithiated with lithium diisopropylamide (LDA) and the resulting lithio derivative has been reacted with electrophiles to obtain 2-alkyl-5-phenyloxazoles.