Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Paper | Regular issue | Vol 31, No. 2, 1990, pp.289-304
Published online, 1st January, 1970
DOI: 10.3987/COM-89-5229
Reactivity of Substituted N-Aminopyridinium Salts and Their Benzologues. A Novel Approach to s-Triazolo[1,5-a]quinolinium and s-Triazolo[5,1-a]isoquinolinium Derivatives

Sándor Bátori, Péter Sándor, and András Messmer*

*Central Research Institute for Chemistry, Hungarian Academy of Sciences, H-1525 Budapest, P.O.Box 17, Hungary

Abstract

The reaction of 1-amino-2-cyanopyridinium perchlorate (1) with triethyl orthoformate gave an ethyl iminoformate derivative (2) which resulted in formation of a 1-iminopyrido-as-triazinium salt (3) in reaction with primary amine, and a formamidino derivative (4) with morpholine gave 2,3-diaza-1,3,5,7-octatetraene (5). The two benzologues of 1,N-aminoquinolinium (9) and N-aminoisoquinolinium (19) gave ethyl iminoformates (10 and 20) and formamidines (14 and 23). In reactions with primary amines these compounds led to s-triazolo[1,5-a]quinolinium (16) and [5,1-a]isoquinolinium (25) salts, respectively.