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Paper | Regular issue | Vol 29, No. 11, 1989, pp.2209-2218
Published online, 1st January, 1970
DOI: 10.3987/COM-89-5163
Synthetic Approach toward Azinomycins

Kenshi Ando, Takae Yamada, and Masayuki Shibuya*

*Faculty of Pharmaceutical Sciences, University of Tokushima, Sho-machi 1, Tokushima 770-8505, Japan

Abstract

The left-half segment 14 of antitumor antibiotics azinomycins A and B was synthesized in optically pure form staning from D-fructose. The dipeptide 18, equivalent to the azinomycin A top-half, was also synthesized via oxazolidinone intermediates.