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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Paper | Regular issue | Vol 29, No. 11, 1989, pp.2141-2148
Published online, 1st January, 1970■ Studies on Aconitum Species. XI. Two New Diterpenoid Alkaloids from Aconitum yesoense var. Macroyesoense (Nakai) Tamura V
Published online, 1st January, 1970
DOI: 10.3987/COM-89-5139
■ Studies on Aconitum Species. XI. Two New Diterpenoid Alkaloids from Aconitum yesoense var. Macroyesoense (Nakai) Tamura V
Koji Wada, Hideo Bando,* Takashi Amiya, and Norio Kawahara
*Hokkaido College of Pharmacy, 7-1 Katsuraoka-cho, Otaru 047-02, Japan
Abstract
A new C20-diterpenoid alkaloid, yesonine (1), a new C19-diterpenoid alkaloid, α-oxobrowniine (2), and five known alkaloids were isolated from Aconitum yesoense var. macroyesoense (Nakai) Tamura. Structures of those new alkaloids were determined on the basis of their spectral and chemical correlation with known alkaloids. Hydrolysis of yesoline (9) and permanganate oxidation of browniine (10) afforded yesonine (1) and α-oxobrowniine (5), respectively.
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