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Communication | Regular issue | Vol 29, No. 8, 1989, pp.1439-1441
Published online, 1st January, 1970
DOI: 10.3987/COM-89-4997
An Alternative Model for the Biogenesis of Xanthanolides

Antonio G. González, Antonio Galindo,* María del Mar Afonso, amd Horacio Mansilla

*Centro de Productos Naturales Orgánicos "Antonio González", Universidad de La Laguna, Avda. Astrofísico Franciso Sánchez, 2, 38206- La Laguna, Tenerife, Spain

Abstract

Hydroperoxide transposition of 4-hydroperoxyguaianolide (10) afforded xanthanolide (12). The possible biogenetic implications of this process are discussed.