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Communication | Regular issue | Vol 29, No. 3, 1989, pp.431-434
Published online, 1st January, 1970
DOI: 10.3987/COM-89-4828
Study on the Structure of Pseudocrown Ether Formed in the Reaction of Ionophore 6-O-BPY1 and Cu+ by 500 MHz 1H Nmr Spectrometry

Tatsuya Nabeshima, Tadashi Inaba, and Naomichi Furukawa*

*Department of Chemistry, University of Tsukuba, 1-1-1 Ten-nodai, Tsukuba-shi, Ibaraki, 305-8571, Japan

Abstract

The structures of ionophore 6-O-bpy 1 and 1-Cu+ complex were studied by 500 MHz 1H nmr spectrometry. Characteristic downfield and upfield shifts of the aromatic
protons, and the methyl and the methylene protons in the picolyl moiety support strongly generation of pseudocrown structure in the 1-Cu+ complex.