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Communication | Regular issue | Vol 27, No. 6, 1988, pp.1345-1348
Published online, 1st January, 1970
DOI: 10.3987/COM-88-4537
Anionic Cycloaddition of Methyl 2,4-Dimethoxy-6-methyl-5-pyrimidinecarboxylate with Acetylenes and Olefins

Akimori Wada,* Hiromi Yamamoto, and Shoichi Kanatomo

*School of Pharmacy, Hokuriku University, 3-Ho, Kanagawa machi, Kanazawa 920-1181, Japan


The lithium salt of methyl 2,4-dimethoxy-6-methyl-5-pyrimidinecarboxylate reacts with electron deficient acetylenes and olefins to afford quinazoline derivatives via anionic cycloaddition in considerable yields.