Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact:

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Regular issue | Vol 27, No. 3, 1988, pp.605-612
Published online, 1st January, 1970
DOI: 10.3987/COM-87-4402
Heterosteroids via Organoiron Complexes: Enantioselectine Synthesis of the 9-(4-Keto-1-methylcyclohex-2-enyl)-8-keto-des-AB-ergosta-14,15-22,23-diene; An Easy Rearrangement of the Title Compound into a 6-Oxo-B-nor-heterosteroid Structure

Enrico Mincione, Paolo Bovicelli, Silvio Cerrini, and Doriano Lamba

*Centro CNR per lo Studio della Chimica delle Sostanze Organiche Naturali, Dipartmento di Chimica, Università degli Studi di Roma "La Sapienza", Piazzale Aldo Moro 5, 00185 Roma, Italy


The synthesis via organoiron complexes of the chiral 9-(4-keto-1-methylcyclohex-2-enyl)-8-keto-des-AB-ergosta-14,15-22,23-diene 13, as well as the rearrangement of 4,13 to 6-oxa B-nor heterosteroids are described.