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Communication | Special issue | Vol 74, No. 1, 2007, pp.239-243
Published online, 30th November, 2007
DOI: 10.3987/COM-07-S(W)70
Synthesis and Structure of One-Dimensional Linear Copper(II) Coordination Polymer Bridged by Dicyclopentanopyrazine

Keiji Nakano, Kengo Miyata, and Masato Kitamura*

*Research Center for Materials Sciences and Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya, Aichi 464-8602, Japan


Crystalline Copper(II) coordination polymers bridged by dicyclopentanopyrazine (1), CuCl2-1, were synthesized. The coordination geometries of the metal centers were tuned to square planar, orthogonal to the plane of the pyrazine ring, by steric hindrance from the methylene chains of pyrazine derivatives.