Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact:

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Special issue | Vol 74, No. 1, 2007, pp.225-231
Published online, 4th December, 2007
DOI: 10.3987/COM-07-S(W)62
Conformational Biasing in 1,3-Oxidative Rearrangements of Dienols

George Majetich,* Hisaya Nishide, Ryan M. Phillips, and Jianhua Yu

*Department of Chemsitry, The University of Georgia, Athens, Georgia 30602, U.S.A.


1-Vinyl-2-cycloalkenols are oxidized to form conjugated dienones in useful yields. Although this oxidative rearrangement is general, severe steric interactions can favor the formation of a conjugated dienal instead of a conjugated dienone. Several heterocyclic analogues were also studied.