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Paper | Special issue | Vol 73, No. 1, 2007, pp.841-855
Published online, 25th September, 2007
DOI: 10.3987/COM-07-S(U)63
Synthesis of a 16-Triazole Phorboxazole A Analog via Intramolecular Triazole Formation

Lu Ying and Craig J. Forsyth*

*Department of Chemistry, The Ohio State University, 100 W 18th Ave., Columbus, OH, 43210, USA


The intramolecular formation of a triazole using a Cu(I)-catalyzed Huisgen [3+2]-cycloaddition between an organic azide and terminal alkyne enabled the preparation of a C16-C18 triazole analog of phorboxazole A.