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Communication | Special issue | Vol 73, No. 1, 2007, pp.159-164
Published online, 17th April, 2007
DOI: 10.3987/COM-07-S(U)1
Synthesis of Fluorescent Solamin for Visualization of Cell Distribution

Naoyoshi Maezaki, Daisuke Urabe, Masahiro Yano, Hiroaki Tominaga, Takekuni Morioka, Naoto Kojima, and Tetsuaki Tanaka*

*Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan


Asymmetric synthesis of fluorescent solamin was accomplished by using highly stereoselective asymmetric alkynylation and Williamson etherification as the key steps, wherein the fluorescent acetogenin with all functionality was firstly synthesized.