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Paper | Regular issue | Vol 75, No. 5, 2008, pp.1123-1131
Published online, 18th January, 2008
DOI: 10.3987/COM-07-11284
Synthesis of Functionalized β-Enamino Compounds by Carbon-Fragment Transfer Reaction of C(2)-Substituted Imidazolidines with Amines

Yongbin Zhang, Donghong Li, Guofu Zhou, Chizhong Xia, and Wei Guo*

*School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China


The substituted imidazolidines (2, 3, 5) and a ring-opening product, N,N,N’2-trisubstituted 2-methyl-ethylenediamines (4), derived from addition of the carbon anions to 1-tosyl-3,4-dimethylimidazolinium iodide (1), were utilized to transfer substituted one-carbon units to various amines to yield a series of functionalized β-enamino compounds.