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Paper | Regular issue | Vol 75, No. 4, 2008, pp.799-838
Published online, 28th December, 2007
DOI: 10.3987/COM-07-11260
Scope and Limitations of the T-Reaction Employing Some Functionalized C-H-Acids and Naturally Occurring Secondary Amines

Constantin Rabong, Christian Hametner, Kurt Mereiter, Victor G. Kartsev, and Ulrich Jordis*

*Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, 1060 Vienna, Austria

Abstract

Scope and limitations of the T-reaction with emphasis on using chiral, natural products as starting materials to prepare novel chiral heterocycles is studied and the diastereoselective introduction of newly formed stereocenters is explained via proposed mechanisms.