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Paper | Special issue | Vol 70, No. 1, 2006, pp.461-476
Published online, 2nd November, 2006
DOI: 10.3987/COM-06-S(W)44
Synthetic Approaches to Polyhydroxy Indolizidines and Related Azabicyclic Scaffolds

Stephen Hanessian,* Eric Therrien, Jayakumar S. Warrier, and Guillaume Charron

*Department of Chemistry, University of Montreal, 2900 Edouard-Montpetit, Montréal, Québec H3C 3J7, Canada


Approaches to the synthesis of unnatural polyhydroxylated indolizidines are described. Key reactions involve addition of 2-(trimethylsilyloxy)furan to iminium salts, and ring-closure metathesis as second alternative.