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Communication | Special issue | Vol 70, No. 1, 2006, pp.77-82
Published online, 26th September, 2006
DOI: 10.3987/COM-06-S(W)19
Investigations of Pd-Catalyzed Aryl Substitution Reactions. A Case Study towards Zoanthenol

David R. Williams,* David C. Ihle, Todd A. Brugel, and Samarjit Patnaik

*Department of Chemistry, Indiana University, 800 East Kirkwood Avenue, Bloomington, IN 47405-7102, U.S.A.

Abstract

Synthesis studies feature results for variations of Heck reaction strategies utilized for aryl substitution processes toward construction of the fully functionalized AB ring system of zoanthenol. A novel intramolecular Michael reaction is described, and the deployment of sensitive allylation reactions are reported.