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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Note | Regular issue | Vol 71, No. 1, 2007, pp.175-180
Published online, 1st December, 2006■ Reactions of Some Dithiinodiquinoline 7-Oxides with Potassium Phenoxide
Published online, 1st December, 2006
DOI: 10.3987/COM-06-10922
■ Reactions of Some Dithiinodiquinoline 7-Oxides with Potassium Phenoxide
Maria J. Maslankiewicz and Andrzej Maslankiewicz*
*Department of Organic Chemistry, The Medical University of Silesia, Jagiellonska 4, 41-200 Sosnowiec, Poland
Abstract
S-Oxides of dithiinodiquinolines (4) and (5) react with potassium phenoxide at γ-quinolinyl-sulfur bond in two manners. Sulfinyl moiety at non-aza-influenced position in sulfoxide (5) significantly activates ortho-sulfanyl substituent towards nucleophilic phenoxy-de-sulfidation to form quinolinethiolate (6A). In the case of sulfoxide (4) with sulfinyl group in aza-activated position, nucleophilic phenoxy-de-sulfinylation occurs to form quinolinesulfenate anion (7A) trapped finally by methylation to products (8), (9) and (10).
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