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Paper | Regular issue | Vol 71, No. 2, 2007, pp.281-287
Published online, 12th January, 2007
DOI: 10.3987/COM-06-10915
The Reactions of Phenoxy Substituted Phosphazenes with 1,3-Propanediol and 3-Amino-1-propanol

Saliha Begeç,* Sümeyya Alatas, and Adem Kiliç

*Department of Chemistry, Faculty of Science and Arts, Inönü University, 44280 Malatya, Turkey


In the present work, two phenoxy substituted phosphazene derivatives, 2-(2,4,6-tri-tert-butylphenoxo)-2,4,4,6,6-pentachlorocyclo-2λ5,4λ5,6λ5-triphosphazatriene (1) and 2-(2,4,6-tri-methylphenoxo)-2,4,4,6,6-pentachlorocyclo-2λ5,4λ5,6λ5-triphosphazatriene, were prepared. The reactions of these derivatives with 3-amino-1-propanol (3) and 1,3-propanediol (4) were studied. Novel phenoxy-substituted; two mono spiro (5, 8), and two dispiro phosphazene derivatives (6, 7) were synthesized. The structures of the compounds were defined by elemental analysis, IR, 1H and 31P NMR spectroscopy.