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Paper | Regular issue | Vol 68, No. 11, 2006, pp.2381-2386
Published online, 12th September, 2006
DOI: 10.3987/COM-06-10832
Synthesis of 2-Aminomethylpyridine Derivatives of Phosphazenes

Saliha Begeç* and Sümeyya Alatas

*Inönü University, Faculty of Science and Arts, Chemistry Department, 44280 Malatya, Turkey

Abstract

Novel cyclophosphazenes (5-8) with pyridine side groups have been synthesized by the reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6 (1), with 2-amino-3-methylpyridine (2), 2-amino-4-methylpyridine (3) and 2-amino-5-methylpyridine (4). Di- and monosubstituted products (5, 6) were obtained from the reaction of 1 with 2 and 3, respectively. Both di- and monosubstituted products (7, 8) were obtained from 2-amino-5-methylpyridine with 1. The structures of the compounds (5-8) were defined by IR, 1H, 13C and 31P NMR spectroscopy and elemental analyses.