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Note | Special issue | Vol 67, No. 2, 2006, pp.797-805
Published online, 18th November, 2005
DOI: 10.3987/COM-05-S(T)72
Pyridine-derived Heterocycles as Potential Photoacylating Reagents

Céline Helgen and Christian G. Bochet*

*Department of Chemistry, University of Fribourg, 9 Ch. du Musée, CH-1700 Fribourg, Switzerland


We prepared several pyridine-derived heterocycles and investigated their photoacylating properties. Among representatives of 4 families of compounds (1-acetyl-7-azaindole, 1-acetyl-7-azaindoline, 2-acetamindpyridine and 2-amidopyrimidines), the 2-aminopyrimidine derivatives were the most promising candidates. Photoacylation of dodecylamine yields up to 47% were obtained, upon irradiation with UV light at 254 nm.