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Paper | Regular issue | Vol 65, No. 7, 2005, pp.1601-1608
Published online, 28th April, 2005
DOI: 10.3987/COM-05-10390
Synthesis and Reactivity of N-Vinyl-1,2,3-dithiazolimines

Vladimir N. Yarovenko,* Andrey A. Es’kov, Pavel A. Kondrashev, Anatolii V. Ignatenko, Igor V. Zavarzin, Lidia G. Vorontsova, Igor P. Sedishev, Mikhail M. Krayushkin, and Zoya A. Starikova

*N. D. Zelinsky Institute of Organic Chemistry, Russia Academy of Science, Leninsky Prospekt 47, Moscow 119991, Russia


A reaction of 4,5-dichloro-1,2,3-dithiazolium chloride (Appel salt) (1) with aziridines (2a-d) affords the N-vinyl-1,2,3-dithiazolimines (3a-d), which can be transformed into thiazole derivatives.