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Communication | Regular issue | Vol 65, No. 3, 2005, pp.523-529
Published online, 25th January, 2005
DOI: 10.3987/COM-04-10306
Conformational Analysis of Dinaphthalene-1-carboxylate Complex of SnIV(tetraphenylporphyrin)

Hajime Iwamoto and Yoshimasa Fukazawa*

*Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan


Conformational analysis of dinaphthalene-1-carboxylate complex of SnIV(tpp) (1) in solution was carried out using temperature dependent 1H NMR spectra and chemical shift simulation method. It was found that two vertical conformers are in equilibrium in solution for 1.