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Paper | Special issue | Vol 61, No. 1, 2003, pp.481-491
Published online, 20th October, 2003
DOI: 10.3987/COM-03-S64
Synthesis of Both Enantiomers of Brevioxime and Determination of Its Absolute Configuration

Yutaka Nishimura, Ken Ishigami, and Takeshi Kitahara*

*Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo 113-8657, Japan

Abstract

Brevioxime is an inhibitor of juvenile hormone biosynthesis, isolated from Penicillium brevicompactum. We synthesized both enantiomers of brevioxime and determined the absolute configuration of natural product as S.