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Paper | Special issue | Vol 61, No. 1, 2003, pp.471-479
Published online, 20th October, 2003
DOI: 10.3987/COM-03-S61
New Chiral Phosphinooxathiolane Ligands for Palladium-catalyzed Asymmetric Allylations

Hiroto Nakano,* Yuko Okuyama, Ryo-suke Takahashi, and Reiko Fujita

*Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, Japan

Abstract

A new chiral phosphinooxathiolane ligands were synthesized and their abilities as chiral catalysts were examined in palladium-catalyzed allylic alkylation and amination.