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Paper | Special issue | Vol 61, No. 1, 2003, pp.125-131
Published online, 14th April, 2003
DOI: 10.3987/COM-03-S4
Enantiocontrolled Total Synthesis of (+)-Heliannuol D via Palladium-mediated Heterocyclization

Hidetoshi Kishuku, Tomoyuki Yoshimura, Toshiyuki Kakehashi, Mitsuru Shindo, and Kozo Shishido*

*Institute for Medicinal Resources, University of Tokushima, 1-78 Sho-machi, Tokushima 770-8505, Japan


An enantiocontrolled total synthesis of (+)-heliannuol D has been accomplished using a palladium-catalyzed cyclization of the seven-membered oxygen containing heterocycle as the key reaction.