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Note | Regular issue | Vol 60, No. 6, 2003, pp.1441-1445
Published online, 21st April, 2003
DOI: 10.3987/COM-03-9756
Design and Synthesis of a Novel Cyclophane as Host for Biologically Relevant Phosphates

Koichi Metori and Muneharu Miyake*

*College of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba 274-8555, Japan

Abstract

A novel water-soluble cyclophane bearing 4-dimethylaminopyridinium groups on the alkyl chains as blanches of 6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine skeleton was synthesized in order to investigate the ability as macrocyclic enzyme models to incorporate biologically relevant phosphates.