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Paper | Special issue | Vol 59, No. 2, 2003, pp.661-668
Published online, 1st January, 1970
DOI: 10.3987/COM-02-S71
Nitrogen Fixation Using Titanium Complex: Reinvestigation of the Reaction Conditions

Masaya Akashi and Miwako Mori*

*Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan


The amounts of Li and TMSCl of a TiX4-Li-TMSCl system for a nitrogen fixation method, previously reported by our group, were examined. As the results, the reactivity of titanium-nitrogen complexes prepared from 4 equiv. of Li and 6 equiv. of TMSCl for Ti(OPr-i)4 (1 equiv.) under an atmosphere of nitrogen was same as that of titanium-nitrogen complexes reported previously.