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Communication | Special issue | Vol 59, No. 1, 2003, pp.97-100
Published online, 1st January, 1970
DOI: 10.3987/COM-02-S36
Regiocontrol in Pd-Catalyzed Allylic Substitution with P,N-Ligand

Kazuhiro Kondo,* Kumiko Kazuta, Atsushi Saitoh, and Yasuoki Murakami*

*School of Pharmaceutical Sciences, Toho University, 2-2-1, Miyama, Funabashi, Chiba 274-8510, Japan


A racemic ligand, (±)-N-[2-(diphenylphosphino)naphthyl]-2-(pyrrolidinylmethyl)piperidine, has been found to exhibit better regioselectivity than the racemic Pfaltz ligand, BINAP and dppp in the palladium-catalyzed regioselective allylic substitution with the use of (E)-1-phenyl-4-alkoxy-2-butenyl acetate as the substrate.