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Communication | Special issue | Vol 59, No. 1, 2003, pp.81-85
Published online, 1st January, 1970
DOI: 10.3987/COM-02-S25
Studies towards the Biomimetic Synthesis of Ginsenoyne L; Efficient Synthesis of 2’-epi-Ginsenoyne L

Jack E. Baldwin,* Robert M. Adlington, Peter J. Wilkinson, Rodolfo Marquez, and Mauro F. A. Adamo

*Dyson Perrins Laboratory, Oxford University, South Parks Road, Oxford OX1 3QY, U.K.

Abstract

The biomimetic synthesis of 2’-epi-gynsenyone L has been accomplished in 7 steps and in good yield through the novel use of bis-acetylenic enones as hetero Diels-Alder dienes for the mild and easy generation of dihydropyrans.