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Paper | Regular issue | Vol 60, No. 4, 2003, pp.865-877
Published online, 10th February, 2003
DOI: 10.3987/COM-02-9695
Synthesis of New Melatonin Analogues from Dimers of Azaindole and Indole by Use of Suzuki Homocoupling

Jérôme Guillard, Carlos Larraya, and Marie-Claude Viaud-Massuard*

*EA 3247 GRCHT Laboratoire de Chimie Organique, UFR des Sciences Pharmaceutiques, Université de Tours, 31 Avenue de Monge, 37200 Tours, France


N-{2-[3’-(2-Acetylaminoethyl)-1H,1’H-[5,5’]biindol-3-yl]- and N-{2-[1’-(2-acetylaminoethyl)-1’H-[5,5’]biindol-1-yl]ethyl}acetamide (2,3) and their analogues in 7-azaindole series (4,5) were synthesized by palladium catalysed reaction starting from indole or 7-azaindole using [1,1’-bis(diphenylphosphino)ferrocene]dichloropalladium, as catalyst.