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Paper | Special issue | Vol 56, No. 1-2, 2002, pp.305-311
Published online, 1st January, 1970
DOI: 10.3987/COM-01-S(K)39
Synthesis and Complexation Behavior of Diaza-18-crown-6 Having Troponyl and Anthryl Groups

Emi Yamamoto, Kanji Kubo,* and Akira Mori*

*Institute of Advanced Material Study, Kyushu University, Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan

Abstract

N-(9-anthrylmethyl)-N’-(tropon-2-yl)diaza-18-crown-6 (4) gave a weak emission, showing that the excited anthracene chromophore was quenched by the diazacrown nitrogen atoms and tropone unit. Diazacrown (4) was found to display unique photophysical properties in the presence of metal salts. Diazacrown (4) exhibited Cu2+ selectivity and in the presence of this cation the host fluorescence intensity was increased by a factor of 7.8.