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Paper | Regular issue | Vol 55, No. 9, 2001, pp.1737-1746
Published online, 1st January, 1970
DOI: 10.3987/COM-01-9279
A Novel Synthesis of 3-Nitropyridine Derivatives from N-Silyl-1-azaallylAnions

Takeo Konakahara,* Ryo Ogawa, Sanae Tamura, Akikazu Kakehi, and Norio Sakai

*Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo, 2641 Yamazaki, Noda, Chiba 278-8510, Japan

Abstract

Seven kinds of 3-nitropyridines were synthesized from N-silyl-1-aza-allyl anions and ethyl 3-etoxy-2-nitropropenoate in good yields, and regio-selectivity of the cyclization was also discussed.