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Communication | Regular issue | Vol 55, No. 7, 2001, pp.1249-1252
Published online, 1st January, 1970
DOI: 10.3987/COM-01-9234
A New Synthesis of 4-Phenylquinolines by Reaction of 2-(α-Bromobenzyl)oxiranes with Aniline Derivatives

Michinori Karikomi, Hiroshi Tsukada, and Takashi Toda*

*Faculty of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya 321-8585, Japan

Abstract

Several 4-phenylquinoline derivatives were synthesized by reaction of (2R*,1’R*)-2-(α-bromobenzyl)oxiranes (1a) with aniline derivatives, and the following treatment of the formed 3-hydroxy-4-phenyl-1,2,3,4-tetrahydroquinolines (2) with the Rydon reagent, and potassium t-butoxide and air oxidation.